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Should I reapply to a university if I get higher grades than expected?
So, whilst you can re-apply next year and might decide to when the time comes, for now it would be advisable to complete the UCAS process.
If you do really well in you A levels you could go into Adjustment and LSE might accept you at this point.
More on Clearing and Adjustment here:
If you abandon UCAS at this point you could regret it and it is a risk you don't need to take.